When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CH3C(O)CH3_JPL-2010(2011)_298K_215-349nm(rec).txt |
| NAME: | dimethyl ketone, acetone, propanone |
| FORMULA: | CH3C(O)CH3 |
| AUTHOR(YEAR): | JPL-2010(2011) |
| T: | 298K |
| λ: | 215-349nm(rec) |
| BIBLIOGRAPHY: |
S.P. Sander, J. Abbatt, J. R. Barker, J. B. Burkholder, R. R. Friedl, D. M. Golden, R. E. Huie, C. E. Kolb, M. J. Kurylo, G. K. Moortgat, V. L. Orkin and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 17",
JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, 2011; http://jpldataeval.jpl.nasa.gov/
|
| COMMENTS: | JPL-2010 recommendation, adopting the earlier recommendation of
S.P. Sander, R.R. Friedl, D.M. Golden, M.J. Kurylo, G.K. Moortgat, H. Keller-Rudek, P.H. Wine, A.R. Ravishankara, C.E. Kolb, M.J. Molina, B.J. Finlayson-Pitts, R.E. Huie, V.L. Orkin, “Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies. Evaluation Number 15“, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, 2006; http://jpldataeval.jpl.nasa.gov/ :
215-349 nm, absorption cross sections at 298 K of T. Gierczak, J.B. Burkholder, S. Bauerle, and A.R. Ravishankara, "Photochemisty of acetone under atmospheric conditions," Chem. Phys. 231, 229-244 (1998); DOI: 10.1016/S0301-0104(98)00006-8 , and temperature coefficients for the new cubic fit σ(T, λ) = σ(298 K, λ) (1 + A T + B T2 + C T3) obtained by personal communication from J.B. Burkholder (May 2005). These values supercede the parameterization given by T. Gierczak, J.B. Burkholder, S. Bauerle, and A.R. Ravishankara, "Photochemisty of acetone under atmospheric conditions," Chem. Phys. 231, 229-244 (1998); DOI: 10.1016/S0301-0104(98)00006-8 . The parameterization is only valid over the temperature range of the experimental data, 298 K to 235 K. Extrapolation outside this temperature range may yield unreliable cross section values. -------------------------------------------------
λ 103 A 105 B 108 C
(nm) (K-1) (K-2) (K-3)
-------------------------------------------------
215 -10.46 8.346 -16.43
216 -9.192 7.357 -14.51
217 -6.233 5.039 -10.01
218 -3.190 2.651 -5.359
219 -1.002 0.9314 -2.003
220 0.4104 -0.1807 0.1679
221 1.567 -1.090 1.936
222 2.962 -2.183 4.058
223 4.839 -3.651 6.909
224 6.940 5.293 10.09
225 8.598 -6.588 12.60
226 9.380 -7.200 13.79
227 9.551 -7.336 14.06
228 9.705 -7.462 14.31
229 10.08 -7.761 14.89
230 10.41 -8.023 15.41
231 10.39 -8.002 15.36
232 10.01 -7.707 14.79
233 9.534 -7.332 14.06
234 9.138 -7.022 13.46
235 8.851 -6.799 13.02
236 8.638 -6.634 12.70
237 8.471 -6.504 12.45
238 8.318 -6.385 12.22
239 8.125 -6.235 11.93
240 7.861 -6.031 11.53
241 7.554 -5.793 11.07
242 7.268 -5.571 10.64
243 7.035 -5.390 10.29
244 6.838 -5.237 9.994
245 6.649 -5.093 9.718
246 6.472 -4.960 9.464
247 6.326 -4.850 9.256
248 6.210 -4.763 9.091
249 6.099 -4.680 8.936
250 5.972 -4.587 8.763
251 5.832 -4.486 8.576
252 5.697 -4.389 8.399
253 5.581 -4.306 8.249
254 5.483 -4.235 8.120
255 5.385 -4.164 7.989
256 5.261 -4.075 7.825
257 5.101 -3.961 7.620
258 4.932 -3.843 7.410
259 4.802 -3.756 7.262
260 4.746 -3.723 7.215
261 4.744 -3.730 7.239
262 4.734 -3.729 7.246
263 4.651 -3.674 7.155
264 4.482 -3.559 6.956
265 4.271 -3.416 6.712
266 4.087 -3.296 6.513
267 3.983 -3.234 6.420
268 3.969 -3.235 6.440
269 4.009 -3.273 6.524
270 4.025 -3.294 6.577
271 3.935 -3.240 6.494
272 3.704 -3.085 6.231
273 3.378 -2.861 5.845
274 3.061 -2.645 5.473
275 2.854 -2.508 5.243
276 2.790 -2.474 5.201
277 2.816 -2.505 5.276
278 2.820 -2.518 5.316
279 2.692 -2.433 5.175
280 2.389 -2.222 4.803
281 1.963 -1.922 4.272
282 1.517 -1.612 3.726
283 1.137 -1.350 3.272
284 0.8530 -1.158 2.943
285 0.6518 -1.023 2.714
286 0.4907 -0.9150 2.531
287 0.3190 -0.7992 2.332
288 0.1109 -0.6586 2.092
289 -0.1230 -0.5036 1.833
290 -0.3698 -0.3426 1.568
291 -0.6430 -0.1615 1.265
292 -0.9625 0.05796 0.8847
293 -1.316 0.3055 0.4472
294 -1.650 0.5349 0.04777
295 -1.905 0.6989 -0.2168
296 -2.084 0.7964 -.3430
297 -2.234 0.8667 -0.4086
298 -2.391 0.9417 -0.4824
299 -2.590 1.055 -0.6387
300 -2.915 1.277 -1.020
301 -3.421 1.649 -1.709
302 -4.008 2.091 -2.543
303 -4.508 2.465 -3.248
304 -4.858 2.715 -3.699
305 -5.120 2.880 -3.959
306 -5.433 3.062 -4.219
307 -6.010 3.429 -4.805
308 -6.986 4.096 -5.954
309 -8.135 4.899 -7.370
310 -8.897 5.415 -8.255
311 -8.923 5.378 -8.097
312 -8.494 5.001 -7.305
313 -8.228 4.754 -6.772
314 -8.445 4.881 -6.959
315 -8.966 5.240 -7.592
316 -9.409 5.528 -8.076
317 -9.584 5.588 -8.085
318 -9.736 5.596 -7.946
319 -10.39 5.958 -8.433
320 -11.80 6.869 -9.933
321 -13.48 7.962 -11.75
322 -14.59 8.600 -12.67
323 -14.98 8.670 -12.47
324 -15.39 8.743 -12.27
325 -16.28 9.187 -12.77
326 -17.09 9.588 -13.21
327 -17.21 9.471 -1.268
328 -16.92 9.048 -11.58
329 -16.66 8.672 -10.62
330 -15.94 7.979 -9.099
331 -13.93 6.340 -5.829
332 -10.93 3.969 -1.214
333 -8.186 1.847 2.840
334 -6.530 0.6289 5.067
335 -5.692 0.1022 5.880
336 -4.656 -0.5382 6.860
337 -2.090 -2.355 10.09
338 3.113 -6.237 17.33
339 11.01 -12.26 28.77
340 20.02 -19.22 42.15
341 27.20 -24.83 53.03
342 29.63 -26.80 56.96
343 25.97 -24.04 51.78
344 16.35 -16.63 37.55
345 3.770 -6.858 18.72
346 -2.414 -1.987 9.304
347 7.880 -9.888 24.53
348 29.52 -26.61 56.78
349 41.03 -35.51 73.95 |
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